Caesium nitrate

Chemical compound CsNO3
Caesium nitrate[1]
Identifiers
CAS Number
  • 7789-18-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 56425 checkY
ECHA InfoCard 100.029.224 Edit this at Wikidata
EC Number
  • 232-146-8
PubChem CID
  • 62674
RTECS number
  • FL0700000
UNII
  • 0K0743KO17
UN number 1451
CompTox Dashboard (EPA)
  • DTXSID2064860 Edit this at Wikidata
InChI
  • InChI=1S/Cs.NO3/c;2-1(3)4/q+1;-1 checkY
    Key: NLSCHDZTHVNDCP-UHFFFAOYSA-N checkY
  • InChI=1/Cs.NO3/c;2-1(3)4/q+1;-1
    Key: NLSCHDZTHVNDCP-UHFFFAOYAE
  • [Cs+].[O-] [N+]([O-])=O
Properties
Chemical formula
CsNO3
Molar mass 194.91 g/mol
Appearance white solid
Density 3.685 g/cm3
Melting point 414 °C (777 °F; 687 K)
Boiling point decomposes, see text
Solubility in water
9.16 g/100 ml (0 °C)
196.8 g/100 ml (100 °C)
Solubility in acetone soluble
Solubility in ethanol slightly soluble
Hazards
GHS labelling:
Ox. Sol. 3
Warning
H272, H315, H319, H335
P210, P220, P221, P280, P370+P378, P501
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
2390 mg/kg (oral, rat)[2]
Related compounds
Other anions
Caesium nitrite
Other cations
Lithium nitrate
Sodium nitrate
Potassium nitrate
Rubidium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Caesium nitrate or cesium nitrate is a salt with the chemical formula CsNO3. An alkali metal nitrate, it is used in pyrotechnic compositions, as a colorant and an oxidizer, e.g. in decoys and illumination flares. The caesium emissions are chiefly due to two powerful spectral lines at 852.113 nm and 894.347 nm.[citation needed]

Caesium nitrate prisms are used in infrared spectroscopy, in x-ray phosphors, and in scintillation counters.[3] It is also used in making optical glasses and lenses.

As with other alkali metal nitrates, caesium nitrate decomposes on gentle heating to give caesium nitrite:

2 CsNO3 → 2 CsNO2 + O2

Caesium also forms two unusual acid nitrates, which can be described as CsNO3·HNO3 and CsNO3·2HNO3 (melting points 100 °C and 36–38 °C respectively).[1]

References

  1. ^ a b Weast, Robert C., ed. (1981). CRC Handbook of Chemistry and Physics (62nd ed.). Boca Raton, FL: CRC Press. p. B-92. ISBN 0-8493-0462-8..
  2. ^ N Iu Tarasenko; E P Lemeshevskaia (1978). "Deĭstvie soedineniĭ tseziia na organizm [Effect of cesium compounds on the body]". Vestn Akad Med Nauk SSSR (in Russian). PMID 695884.
  3. ^ Budavari, Susan, ed. (2001), The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals (13th ed.), Merck, p. 345, ISBN 0911910131.
  • v
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  • CsBi2
  • CsBr
  • CsCl
  • CsCN
  • CsClO4
  • Cs2CrO4
  • Cs2CoF6
  • Cs2CuF6
  • CsF
  • CsH
  • CsI
  • CsI3
  • CsLiB6O10
  • CsN3
  • CsNO3
  • CsOH
  • Cs2CO3
  • CsHCO3
  • Cs2C2O4
  • Cs2SO4
  • Cs2S
  • Cs2SeO4
  • Cs2Se
  • CsC2H3O2
  • Cs2O
  • Cs2O2
  • Cs2P5
  • Cs2O3
  • CsO2
  • CsO3
  • Cs2Te
  • Cs2TiO3
  • Cs2WO4
  • CsAu
  • C18H35CsO2
  • CsMnO4
  • CsTcO4
  • Cs2B12H12
  • CsHSO4
  • Cs3Bi2Br9
  • CsXeF7
  • Cs2AgBiBr6
  • Cs2ZrO3
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Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 RONO2
+CO3
+C2O4
NO3-
NH4NO3
HOONO2 FNO3
+F
Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)4
Si P +SO4 ClONO2
+Cl
Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br
Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2
Pd(NO3)4
AgNO3
Ag(NO3)2
Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3
Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt(NO3)2 Au(NO3)3 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No


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