Fluoride nitrate

Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.

List

name formula mw crystal system space group unit cell Å volume density comment reference
L-Argininium L-Arg2+•F−•NO3− triclinic P1 a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2 [1]
2L-Arg2+•F−•3NO3−•HF orthorhombic P212121 a=7.3960 b=12.8672 c=26.990 Z=4 [1]
L-histidine L-His2+•F−•NO3− [1]
[Cr(NH3)5F](NO3)2 [2]
hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate [Co(Im)6][F·NO3•(H2O)4] hexagonal P63/m a 8.972 c 21.077 Z=2 1469.3 1.402 pink [3]
[Co(NH3)4(OH)F]NO3 [4]
[Co(NH3)5F](NO3)2 [5]
[Co(NH3)6]F(NO3)2 [4]
[Co(en)2F2]NO3 [4]
[As(ONO2)4]+[AsF6]− pale yellow; hydroscopic [6]
[Zr2F3OH(NO3)2(H2O)5]2+ in solution [7]
SnF2(ONO2)2 [6]
SnF3(ONO2) stable < 40°C; hydroscopic [6]
SbF(ONO2)4 [6]
SbF3(ONO2)2 [6]
Xenon fluoride nitrate FXeONO2 monoclinic a = 4.6663 b = 8.799 c = 9.415 β = 90.325° 386.6 3.648
CsFHONO2 [8]
[HfF4NO3]− in solution [7]
[HfF3(NO3)2]− in solution [7]
Hg3O2(NO3)F orthorhombic Pnma a=7.547 b=10.990 c=6.9906 birefringence Δn = 0.23 @ 1064 nm [9]
Pb3F5NO3 triclinic P1 a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517° layered; stable to 450°C [10][11]
Pb(OF)Cu3(SeO3)2(NO3) trigonal R3m a 6.6973 c 18.5548 Z=3 720.75 5.175 yellow; stable to 400°C [12]
PbCdF(SeO3)(NO3) orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 NLO 2.6×KDP; band gap 4.42 eV [13]
BaPb2F5NO3 [14]
Bi2OF3(NO3) hexagonal P63/m band gap 3.5 eV [15]
Bi6O6F5(NO3) trigonal R3 band gap 4.0 eV [15]
[(UO2)4F13][Sr3(H2O)8](NO3)·H2O 1814.13 triclinic P1 a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2. 1468.1 4.105 yellow [16]

References

  1. ^ a b c Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3.
  2. ^ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines". Physical Review B. 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829.
  3. ^ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n ] in metal complex crystals". CrystEngComm. 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033.
  4. ^ a b c Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944.
  5. ^ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia". Journal of Solution Chemistry. 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. S2CID 97374902.
  6. ^ a b c d e Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn". Chemische Berichte. 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940.
  7. ^ a b c Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations". European Journal of Inorganic Chemistry. 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. S2CID 233628149.
  8. ^ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2]−". Journal of Inorganic and Nuclear Chemistry. 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9.
  9. ^ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy". Inorganic Chemistry Frontiers. 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553.
  10. ^ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride". Crystal Growth & Design. 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483.
  11. ^ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange". Journal of the American Chemical Society. 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835.
  12. ^ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice". Chemical Communications. 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. S2CID 222235842.
  13. ^ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units". Inorganic Chemistry. 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. S2CID 52136440.
  14. ^ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3".
  15. ^ a b Cho, Eun Jeong; Oh, Seung-Jin; Jo, Hongil; Lee, Junsu; You, Tae-Soo; Ok, Kang Min (2019-02-04). "Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties". Inorganic Chemistry. 58 (3): 2183–2190. doi:10.1021/acs.inorgchem.8b03343. ISSN 0020-1669.
  16. ^ Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 ][Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O". Inorganic Chemistry. 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437.
  • v
  • t
  • e
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
LiF BeF2 BF
BF3
B2F4
+BO3 		CF4
CxFy
+CO3 		NF3
FN3
N2F2
NF
N2F4
NF2
?NF5 		OF2
O2F2
OF
O3F2
O4F2
?OF4 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4 		ClF
ClF3
ClF5 		?ArF2
?ArF4
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
?CrF6 		MnF2
MnF3
MnF4
?MnF5 		FeF2
FeF3
FeF4 		CoF2
CoF3
CoF4 		NiF2
NiF3
NiF4 		CuF
CuF2
?CuF3 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6
+SeO3 		BrF
BrF3
BrF5 		KrF2
?KrF4
?KrF6
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF4
MoF5
MoF6 		TcF4
TcF
5
TcF6 		RuF3
RuF
4
RuF5
RuF6 		RhF3
RhF4
RhF5
RhF6 		PdF2
Pd[PdF6]
PdF4
?PdF6 		Ag2F
AgF
AgF2
AgF3 		CdF2 InF
InF3 		SnF2
SnF4 		SbF3
SbF5 		TeF4
?Te2F10
TeF6
+TeO3 		IF
IF3
IF5
IF7
+IO3 		XeF2
XeF4
XeF6
?XeF8
CsF BaF2   LuF3 HfF4 TaF5 WF4
WF5
WF6 		ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6
?OsF
7
?OsF
8 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
Pt[PtF6]
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
?AuF6
AuF5•F2 		Hg2F2
HgF2
?HgF4 		TlF
TlF3 		PbF2
PbF4 		BiF3
BiF5 		?PoF2
PoF4
PoF6 		AtF
?AtF3
?AtF5 		RnF2
?RnF
4
?RnF
6
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3
PrF4 		NdF2
NdF3
NdF4 		PmF3 SmF2
SmF3 		EuF2
EuF3 		GdF3 TbF3
TbF4 		DyF2
DyF3
DyF4 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3
AcF3 ThF3
ThF4 		PaF4
PaF5 		UF3
UF4
UF5
UF6 		NpF3
NpF4
NpF5
NpF6 		PuF3
PuF4
PuF5
PuF6 		AmF2
AmF3
AmF4
? AmF6 		CmF3
CmF4
 ?CmF6 		BkF3
BkF
4 		CfF3
CfF4 		EsF3
EsF4
?EsF6 		Fm Md No
  • v
  • t
  • e
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 RONO2
+CO3
+C2O4 		NO3-
NH4NO3 		HOONO2 FNO3
+F 		Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)−4 		Si P +SO4 ClONO2
+Cl 		Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3 		Co(NO3)2
Co(NO3)3 		Ni(NO3)2 CuNO3
Cu(NO3)2 		Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br 		Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2
Pd(NO3)4 		AgNO3
Ag(NO3)2 		Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3 		Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt(NO3)2 Au(NO3)3 Hg2(NO3)2
Hg(NO3)2 		TlNO3
Tl(NO3)3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4 		Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No