Telluride iodide

Class of chemical compounds

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.

List

name formula system space group unit cell volume density properties ref
Copper telluride iodide CuTeI tetrahedral I41/amd a = 17.170, c = 4.876, and Z = 16 Cu+1 ion conductor; metallic grey [2][3]
(CuI)3Cu2TeS3 P3121 [1]
gallium telluride iodide GaTeI orthorhombic band gap 2.55 [1]
Ge40.0Te5.3I8 cubic Pm3n a=10.815 Z = 1 1265.0 6.023 band gap 0.8 eV; clathrate [4]
α-Arsenic telluride iodide AsTeI monoclinic P21 a=8.965 b=4.042 c=10.341 β=90.75 Z=4 5.84 melt 281°C black [5]
β-Arsenic telluride iodide AsTeI cubic Fm3m a=5.791 Z=2 5.63 black metallic [5]
As4Te5I2 monoclinic a=14.58 b=4.00 c=12.26 β=95.0 Z=2 5.51 melt 303 °C metallic [5]
triniobium telluride heptaiodide Nb3TeI7 [1]
NbTe4I P21/c a=7.695 b=15.393 c=13.438 β=100.84 Z=8 1563.2 6.205 black metallic [6]
diniobium hexatelluride iodide Nb2Te6I P21/c a=9.197 b=13.387 c=9.651 β=112.36 1093.8 6.548 [1][7]
Nb4Te12I monoclinic C12/c1 a=21.957 b=6.147 c=19.925 β=122.40 Z=4 2270.6 5.8 black [8]
Nb4Te17I4 monoclinic C2/c a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4 black metallic [9]
Mo3Tel0Il0 [1]
[Mo3Se7(TeI3)I2]I monoclinic P23/n a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 2208.3 5.202 [1][10]
[Mo3Te7(TeI3)3]2(I)(TeI3) triclinic P1 a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z= 1868.4 5.374 [1][10]
Palladium telluride iodide PdTeI a=7.821 c=5.659 brass yellow [11][12]
Ag23Te12I orthorhombic Pnnm honeycomb Te [1]
Ag19Te6Br5.4I1.6 orthorhombic Pnma electric conductor [1]
indium telluride iodide InTeI monoclinic P21/c [13]
Antimony telluride iodide SbTeI triclinic P1 [1]
(Sb2Te2)I[AlI4] monoclinic P21/n [1]
La2TeI2 rhombohedral R3m a = 4.5074 c = 32.528 Z = 3 metallic [1][14]
Er17.3Te24I8 Fd3m a=12.020 [15]
Ta3TeI7 hexagonal P63mc [1]
[TaTe4]4[PtI6]I2 triclinic P1 a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1 977.65 [16]
TaTe4I triclinic P1 a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2 381.8 7.118 black [6]
W2Cl12Te6I2 [17]
Gold telluride iodide AuITe monoclinic a=7.317 b=7.626 c=7.249 β=106.33 7.73 semiconductor band gap 0.9 grey melt 360°C [18]
Gold telluride diiodide AuITe2 orthorhombic Pmmb a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2 241.9 7.989 silvery white conductor melt 440°C [19]
Hg3Te2I2 greyish red [1]
Hg3Te2BrI monoclinic C2 18.376 b=9.587 c=10.575 β=100.11° [20]
Hg3TeI4 cubic F43m a=6.244 Z=(80% partial occupancy) 243.4 7.03 decompose 273°C dark ruby red [21]
Bismuth telluride iodide BiTeI P3m1 / Pnma over 3.9 GPa Weyl semimetal; under semimetal [1]
ThTe2I2 monoclinic C2/m a  = 7.642 b  = 14.336 c  = 7.727 and β = 111.27° Z = 4 [22]
[Ta7(Se2)14][U2I10]2 orthorhombic Cccm a = 21.5134 b = 22.1619 and c = 16.7834 Z=4 [23]

References

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  3. ^ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" [Telluride halides of copper with high ionic partial conductivity]. Zeitschrift für anorganische und allgemeine Chemie (in German). 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.
  4. ^ Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Dikarev, Evgeny V.; Shevelkov, Andrei V. (2006-05-01). "Ge 40.0 Te 5.3 I 8 : synthesis, crystal structure, and properties of a new clathrate-I compound". Zeitschrift für Kristallographie - Crystalline Materials. 221 (5–7): 527–532. Bibcode:2006ZK....221..527K. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. S2CID 59375600.
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  6. ^ a b Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur". Chemische Berichte (in German). 125 (10): 2165–2170. doi:10.1002/cber.19921251002.
  7. ^ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group". Inorganic Chemistry. 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.
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  9. ^ Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride". Chemische Berichte (in German). 127 (1): 11–14. doi:10.1002/cber.19941270103.
  10. ^ a b Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
  11. ^ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study". Physical Review B. 91 (24): 245204. arXiv:1506.05687. Bibcode:2015PhRvB..91x5204G. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. S2CID 118467913.
  12. ^ Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal". Angewandte Chemie International Edition in English. 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.
  13. ^ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials. 18 (10): 2538–2544. doi:10.1021/cm060226m.
  14. ^ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties". Inorganic Chemistry. 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.
  15. ^ Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems". Journal of Solid State Chemistry. 139 (1): 57–65. doi:10.1006/jssc.1998.7807.
  16. ^ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B. 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117. S2CID 93309355.
  17. ^ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
  18. ^ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold". Journal of the Less Common Metals. 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.
  19. ^ Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I". Journal of Solid State Chemistry. 10 (2): 175–181. Bibcode:1974JSSCh..10..175H. doi:10.1016/0022-4596(74)90024-3.
  20. ^ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2". Journal of Alloys and Compounds. 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
  21. ^ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4". Zeitschrift für anorganische und allgemeine Chemie. 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.
  22. ^ Rocker, Frank; Tremel, Wolfgang (2001). "Synthesis and Structure of ThTe2I2". Zeitschrift für anorganische und allgemeine Chemie. 627 (6): 1305–1308. doi:10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749.
  23. ^ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2". Zeitschrift für anorganische und allgemeine Chemie. 636 (3–4): 440–442. doi:10.1002/zaac.200900416.
  • v
  • t
  • e
Salts and covalent derivatives of the telluride ion
H2Te He
Li2Te BeTe B CTe2
(CH3)2Te 		(NH4)2Te O F Ne
Na2Te MgTe Al2Te Si P0.8Te0.2 S Cl Ar
K2Te CaTe Sc2Te3 Ti VTe2 CrTe
Cr2Te3 		MnTe
MnTe2 		FeTe CoTe NiTe Cu2Te
CuTe
CuTe2 		ZnTe GaTe
Ga2Te3
-Ga 		GeTe
-Ge 		As2Te3
As4Te3
+As 		Se +Br Kr
Rb2Te SrTe Y2Te3 ZrTe5 NbTe2 MoTe2 Tc Ru Rh Pd Ag2Te CdTe In2Te3 SnTe
SnTe2 		Sb2Te3 Te2-
Te2-
n 		I Xe
Cs2Te BaTe * LuTe
Lu2Te3 		HfTe5 TaTe2 WTe2
WTe3 		ReTe2 Os Ir Pt AuxTey HgTe Tl2Te PbTe Bi2Te3 Po At Rn
Fr RaTe ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaTe
La2Te3 		CeTe
Ce2Te3 		PrTe
Pr2Te3 		NdTe
Nd2Te3 		Pm SmTe
Sm2Te3 		EuTe
Eu2Te3 		GdTe
Gd2Te3 		TbTe
Tb2Te3 		DyTe
Dy2Te3 		HoTe
Ho2Te3 		ErTe
Er2Te3 		TmTe
Tm2Te3 		YbTe
Yb2Te3
** Ac ThTe2 Pa UTe2 Np Pu Am Cm Bk Cf Es Fm Md No
  • v
  • t
  • e
Salts and covalent derivatives of the iodide ion
HI
+H 		He
LiI BeI2 BI3
+BO3 		CI4
+C 		NI3
NH4I
+N 		I2O4
I2O5
I4O9 		IF
IF3
IF5
IF7 		Ne
NaI MgI2 AlI
AlI3 		SiI4 PI3
P2I4
+P
PI5 		S2I2 ICl
ICl3 		Ar
KI CaI2 ScI3 TiI2
TiI3
TiI4 		VI2
VI3 		CrI2
CrI3 		MnI2 FeI2
FeI3 		CoI2 NiI2
-Ni 		CuI ZnI2 GaI
GaI3 		GeI2
GeI4
+Ge 		AsI3
As2I4
+As 		Se IBr
IBr3 		Kr
RbI
RbI3 		SrI2 YI3 ZrI2
ZrI3
ZrI4 		NbI4
NbI5 		MoI2
MoI3 		TcI3 RuI3 RhI3 PdI2 AgI CdI2 InI
InI3 		SnI2
SnI4 		SbI3
+Sb 		TeI4
+Te 		I−
I−
3 		Xe
CsI
CsI3 		BaI2   LuI3 HfI3
HfI4 		TaI4
TaI5 		WI2
WI3
WI4 		ReI3
ReI
4 		OsI
OsI2
OsI3 		IrI3
IrI
4 		PtI2
PtI4 		AuI
AuI3 		Hg2I2
HgI2 		TlI
TlI3 		PbI2 BiI3 PoI2
PoI4 		AtI Rn
Fr RaI2   Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaI2
LaI3 		CeI2
CeI3 		PrI2
PrI3 		NdI2
NdI3 		PmI3 SmI2
SmI3 		EuI2
EuI3 		GdI2
GdI3 		TbI3 DyI2
DyI
3 		HoI3 ErI3 TmI2
TmI3 		YbI2
YbI3
AcI3 ThI2
ThI3
ThI4 		PaI4
PaI5 		UI3
UI4 		NpI3 PuI3 AmI2
AmI3 		CmI3 BkI
3 		CfI
2
CfI
3 		EsI2
EsI3 		Fm Md No